Synthetic Studies towards the Africanane Sesquiterpenes via the Cope Rearrangement of gem-Dimethyl-Substituted Divinyl Cyclopropanes
نویسندگان
چکیده
منابع مشابه
The Cope rearrangement of gem-dimethyl substituted divinylcyclopropanes.
The reactivity of a range of substituted divinylcyclopropanes towards the thermal Cope rearrangement has been examined. The effects of gem-dimethyl substitution on the cyclopropane, the alkene geometry, the relative stereochemistry of the cyclopropane and the steric and electronic effects of a range of functional groups were all examined, and the methods developed were used to synthesise a rang...
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ژورنال
عنوان ژورنال: Synlett
سال: 2015
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-0035-1560176